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modified: 02/13/06
More Than You've Ever Wanted To Know About
Motor Oil
by Ed Hackett
edh@maxey.unr.edu
Choosing the best motor oil is a topic...
that comes up frequently in discussions between
motorheads, whether they are talking about motorcycles or cars. The
following article is intended to help you make a choice based on
more than the advertising hype.
Oil companies provide data on their oils most often referred to
as "typical inspection data". This is an average of the
actual physical and a few common chemical properties of their oils.
This information is available to the public through their
distributors or by writing or calling the company directly. I have
compiled a list of the most popular, premium oils so that a ready
comparison can be made. If your favorite oil is not on the list get
the data from the distributor and use what I have as a data base.
This article is going to look at six of the most important
properties of a motor oil readily available to the public:
viscosity, viscosity index (VI), flash point, pour point, % sulfated
ash, and % zinc.
Viscosity is a measure of the "flowability" of an oil.
More specifically, it is the property of an oil to develop and
maintain a certain amount of shearing stress dependent on flow, and
then to offer continued resistance to flow. Thicker oils generally
have a higher viscosity, and thinner oils a lower viscosity. This is
the most important property for an engine. An oil with too low a
viscosity can shear and loose film strength at high temperatures. An
oil with too high a viscosity may not pump to the proper parts at
low temperatures and the film may tear at high rpm.
The weights given on oils are arbitrary numbers assigned by the
S.A.E. (Society of Automotive Engineers). These numbers correspond
to "real" viscosity, as measured by several accepted
techniques. These measurements are taken at specific temperatures.
Oils that fall into a certain range are designated 5, 10, 20, 30,
40, 50 by the S.A.E. The W means the oil meets specifications for
viscosity at 0 F and is therefore suitable for Winter use.
The following chart shows the relationship of "real"
viscosity to their S.A.E. assigned numbers. The relationship of gear
oils to engine oils is also shown.
_______________________________________________________________
| |
| SAE Gear Viscosity Number |
| ________________________________________________________ |
| |75W |80W |85W| 90 | 140 | |
| |____|_____|___|______________|________________________| |
| |
| SAE Crank Case Viscosity Number |
| ____________________________ |
| |10| 20 | 30 | 40 | 50 | |
| |__|_____|____|_____|______| |
______________________________________________________________
2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42
viscosity cSt @ 100 degrees C
Multi viscosity oils work like this: Polymers are added to a
light base (5W, 10W, 20W), which prevent the oil from thinning as
much as it warms up. At cold temperatures the polymers are coiled up
and allow the oil to flow as their low numbers indicate. As the oil
warms up the polymers begin to unwind into long chains that prevent
the oil from thinning as much as it normally would. The result is
that at 100 degrees C the oil has thinned only as much as the higher
viscosity number indicates. Another way of looking at multi-vis oils
is to think of a 20W-50 as a 20 weight oil that will not thin more
than a 50 weight would when hot.
Multi viscosity oils are one of the great improvements in oils,
but they should be chosen wisely. Always use a multi grade with the
narrowest span of viscosity that is appropriate for the temperatures
you are going to encounter. In the winter base your decision on the
lowest temperature you will encounter, in the summer, the highest
temperature you expect. The polymers can shear and burn forming
deposits that can cause ring sticking and other problems. 10W-40 and
5W-30 require a lot of polymers (synthetics excluded) to achieve
that range. This has caused problems in diesel engines, but fewer
polymers are better for all engines. The wide viscosity range oils,
in general, are more prone to viscosity and thermal breakdown due to
the high polymer content. It is the oil that lubricates, not the
additives. Oils that can do their job with the fewest additives are
the best.
Very few manufactures recommend 10W-40 any more, and some
threaten to void warranties if it is used. It was not included in
this article for that reason. 20W-50 is the same 30 point spread,
but because it starts with a heavier base it requires less viscosity
index improvers (polymers) to do the job. AMSOIL can formulate their
10W-30 and 15W-40 with no viscosity index improvers but uses some in
the 10W-40 and 5W-30. Mobil 1 uses no viscosity improvers in their
5W-30, and I assume the new 10W-30. Follow your manufacturer's
recommendations as to which weights are appropriate for your
vehicle.
Viscosity Index is an empirical number indicating the rate of
change in viscosity of an oil within a given temperature range.
Higher numbers indicate a low change, lower numbers indicate a
relatively large change. The higher the number the better. This is
one major property of an oil that keeps your bearings happy. These
numbers can only be compared within a viscosity range. It is not an
indication of how well the oil resists thermal breakdown.
Flash point is the temperature at which an oil gives off vapors
that can be ignited with a flame held over the oil. The lower the
flash point the greater tendency for the oil to suffer vaporization
loss at high temperatures and to burn off on hot cylinder walls and
pistons. The flash point can be an indicator of the quality of the
base stock used. The higher the flash point the better. 400 F is the
minimum to prevent possible high consumption. Flash point is in
degrees F.
Pour point is 5 degrees F above the point at which a chilled oil
shows no movement at the surface for 5 seconds when inclined. This
measurement is especially important for oils used in the winter. A
borderline pumping temperature is given by some manufacturers. This
is the temperature at which the oil will pump and maintain adequate
oil pressure. This was not given by a lot of the manufacturers, but
seems to be about 20 degrees F above the pour point. The lower the
pour point the better. Pour point is in degrees F.
% sulfated ash is how much solid material is left when the oil
burns. A high ash content will tend to form more sludge and deposits
in the engine. Low ash content also seems to promote long valve
life. Look for oils with a low ash content.
% zinc is the amount of zinc used as an extreme pressure, anti-
wear additive. The zinc is only used when there is actual metal to
metal contact in the engine. Hopefully the oil will do its job and
this will rarely occur, but if it does, the zinc compounds react
with the metal to prevent scuffing and wear. A level of .11% is
enough to protect an automobile engine for the extended oil drain
interval, under normal use. Those of you with high revving, air
cooled motorcycles or turbo charged cars or bikes might want to look
at the oils with the higher zinc content. More doesn't give you
better protection, it gives you longer protection if the rate of
metal to metal contact is abnormally high. High zinc content can
lead to deposit formation and plug fouling.
The Data:
Listed alphabetically --- indicates the data was not available
Brand VI Flash Pour %ash %zinc
20W-50
AMSOIL 136 482 -38 <.5 ---
Castrol GTX 122 440 -15 .85 .12
Exxon High Performance 119 419 -13 .70 .11
Havoline Formula 3 125 465 -30 1.0 ---
Kendall GT-1 129 390 -25 1.0 .16
Pennzoil GT Perf. 120 460 -10 .9 ---
Quaker State Dlx. 155 430 -25 .9 ---
Red Line 150 503 -49 --- ---
Shell Truck Guard 130 450 -15 1.0 .15
Spectro Golden 4 174 440 -35 --- .15
Spectro Golden M.G. 174 440 -35 --- .13
Unocal 121 432 -11 .74 .12
Valvoline All Climate 125 430 -10 1.0 .11
Valvoline Turbo 140 440 -10 .99 .13
Valvoline Race 140 425 -10 1.2 .20
Valvoline Synthetic 146 465 -40
20W-40
Castrol Multi-Grade 110 440 -15 .85 .12
Quaker State 121 415 -15 .9 ---
15W-50
Chevron 204 415 -18 .96 .11
Mobil 1 170 470 -55 --- ---
Mystic JT8 144 420 -20 1.7 .15
Red Line 152 503 -49 --- ---
5W-50
Castrol Syntec 180 437 -45 1.2 .10
Quaker State Synquest 173 457 -76 --- ---
Pennzoil Performax 176 --- -69 --- ---
5W-40
Havoline 170 450 -40 1.4 ---
15W-40
AMSOIL 135 460 -38 <.5 ---
Castrol 134 415 -15 1.3 .14
Chevron Delo 400 136 421 -27 1.0 ---
Exxon XD3 --- 417 -11 .9 .14
Exxon XD3 Extra 135 399 -11 .95 .13
Kendall GT-1 135 410 -25 1.0 .16
Mystic JT8 142 440 -20 1.7 .15
Red Line 149 495 -40 --- ---
Shell Rotella w/XLA 146 410 -25 1.0 .13
Valvoline All Fleet 140 --- -10 1.0 .15
Valvoline Turbo 140 420 -10 .99 .13
10W-30
AMSOIL 142 480 -70 <.5 ---
Castrol GTX 140 415 -33 .85 .12
Chevron Supreme 150 401 -26 .96 .11
Exxon Superflo Hi Perf 135 392 -22 .70 .11
Exxon Superflo Supreme 133 400 -31 .85 .13
Havoline Formula 3 139 430 -30 1.0 ---
Kendall GT-1 139 390 -25 1.0 .16
Mobil 1 160 450 -65 --- ---
Pennzoil PLZ Turbo 140 410 -27 1.0 ---
Quaker State 156 410 -30 .9 ---
Red Line 139 475 -40 --- ---
Shell Fire and Ice 155 410 -35 .9 .12
Shell Super 2000 155 410 -35 1.0 .13
Shell Truck Guard 155 405 -35 1.0 .15
Spectro Golden M.G. 175 405 -40 --- ---
Unocal Super 153 428 -33 .92 .12
Valvoline All Climate 130 410 -26 1.0 .11
Valvoline Turbo 135 410 -26 .99 .13
Valvoline Race 130 410 -26 1.2 .20
Valvoline Synthetic 140 450 -40
5W-30
AMSOIL 168 480 -76 <.5 ---
Castrol GTX 156 400 -35 .80 .12
Chevron Supreme 202? 354 -46 .96 .11
Chevron Supreme Synt. 165 446 -72 1.1 .12
Exxon Superflow HP 148 392 -22 .70 .11
Havoline Formula 3 158 420 -40 1.0 ---
Mobil 1 165 445 -65 --- ---
Mystic JT8 161 390 -25 .95 .1
Quaker State 165 405 -35 .9 ---
Red Line 151 455 -49 --- ---
Shell Fire and Ice 167 405 -35 .9 .12
Unocal 151 414 -33 .81 .12
Valvoline All Climate 135 405 -40 1.0 .11
Valvoline Turbo 158 405 -40 .99 .13
Valvoline Synthetic 160 435 -40
All of the oils above meet current SG/CD
ratings and all vehicle manufacture's warranty requirements in the
proper viscosity. All are "good enough", but those with
the better numbers are icing on the cake.
The synthetics offer the only truly significant differences, due
to their superior high temperature oxidation resistance, high film
strength, very low tendency to form deposits, stable viscosity base,
and low temperature flow characteristics. Synthetics are superior
lubricants compared to traditional petroleum oils. You will have to
decide if their high cost is justified in your application.
The extended oil drain intervals given by the vehicle
manufacturers (typically 7500 miles) and synthetic oil companies (up
to 25,000 miles) are for what is called normal service. Normal
service is defined as the engine at normal operating temperature, at
highway speeds, and in a dust free environment. Stop and go, city
driving, trips of less than 10 miles, or extreme heat or cold puts
the oil change interval into the severe service category, which is
3000 miles for most vehicles. Synthetics can be run two to three
times the mileage of petroleum oils with no problems. They do not
react to combustion and combustion by-products to the extent that
the dead dinosaur juice does. The longer drain intervals possible
help take the bite out of the higher cost of the synthetics. If your
car or bike is still under warranty you will have to stick to the
recommended drain intervals. These are set for petroleum oils and
the manufacturers make no official allowance for the use of
synthetics.
Oil additives should not be used. The oil companies have gone to
great lengths to develop an additive package that meets the
vehicle's requirements. Some of these additives are synergistic,
that is the effect of two additives together is greater than the
effect of each acting separately. If you add anything to the oil you
may upset this balance and prevent the oil from performing to
specification.
The numbers above are not, by any means, all there is to
determining what makes a top quality oil. The exact base stock used,
the type, quality, and quantity of additives used are very
important. The given data combined with the manufacturer's claims,
your personal experience, and the reputation of the oil among others
who use it should help you make an informed choice. |